Fluorescent probe mimicking multiple logic gates and a molecular keypad lock upon interaction with Hg2+ and bovine serum albumin.
نویسندگان
چکیده
The output fluorescence exhibited by an intramolecular charge transfer fluorescent probe 1 providing different chemical inputs mimicked multiple logic gates. A molecular keypad lock security device authorizing password entries (logic memory) and capable of solving crossword puzzles has been constructed by computing the output emission of 1 upon chemical inputs of BSA and Hg(2+). Based on logic operations the devised fluorescent keypad lock could be unlocked upon entering a correct sequence of password, 'BHU'.
منابع مشابه
A versatile water soluble fluorescent probe for ratiometric sensing of Hg2+ and bovine serum albumin.
A novel tetraazamacrocycle fluorescent sensor (6-(1-(dimethylamino)-5-naphthalene sulfonyl)-3,6,9,15-tetraazabicyclo[9.3.1] pentadeca-1(15),11,13-triene, 1) has been designed and prepared, which can be utilized for selective and ratiometric sensing of Hg(2+) and bovine serum albumin (BSA) with two different responsive modes in aqueous solution at physiological pH (50 mM Tris-HCl, pH 7.6). Above...
متن کاملSpectroscopic, Thermodynamic and Molecular Docking Studies on Interaction of Toxic Azo Dye with Bovine Serum Albumin
Investigation on interaction of azo dyes with bovine serum albumin as carrier protein will be important in the field of toxicology because of distribution and transportation of dyes in blood. In this regard, the interaction between the azo dye, trisodium (4E)-3-oxo-4-[(4- sulfonato-1- naphthyl) hydrazono] naphthalene-2,7-disulfonate (C20H11N2Na3O10S3), known as Amaranth and bovine serum albumin...
متن کاملAll-Photonic Molecular Keypad Lock
Herein we demonstrate a molecular triad (1, Figure 1) comprising two photochromic units and a fluorescent porphyrin reporter that functions as an all-photonic keypad lock. The lock is a molecular automaton that opens only when exposed to one out of 8 possible 2-digit codes, can be reset many times, and can be activated remotely. Investigations of molecular approaches to logic operations began w...
متن کاملMolecules with a sense of logic: a progress report.
In this tutorial review, the most recent developments in the field of molecular logic and information processing are discussed. Special emphasis is given to the report of progress in the concatenation of molecular logic devices and switches, the design of memory systems working according to the principles of sequential logic, the mimicking of transistors, and the research on photochromic platfo...
متن کاملFluorescent Gold Nanoprobes for the Sensitive and Selective Detection for Hg2+
A simple, cost-effective yet rapid and sensitive sensor for on-site and real-time Hg(2+) detection based on bovine serum albumin functionalized fluorescent gold nanoparticles as novel and environmentally friendly fluorescent probes was developed. Using this probe, aqueous Hg(2+) can be detected at 0.1 nM in a facile way based on fluorescence quenching. This probe was also applied to determine t...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- The Analyst
دوره 137 15 شماره
صفحات -
تاریخ انتشار 2012